• Title of article

    Asymmetric synthesis of functionalised cyclopentenones via organocatalysed rearrangement and enzymatic resolution of pyranones

  • Author/Authors

    Nunes، نويسنده , , Joمo P.M. and Afonso، نويسنده , , Carlos A.M. and Caddick، نويسنده , , Stephen، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2009
  • Pages
    3
  • From page
    3706
  • To page
    3708
  • Abstract
    A direct asymmetric synthesis of a trans-4,5-difunctionalised cyclopentenone derivative has been achieved in 55% yield and 80% ee by organocatalysed rearrangement of a pyranone in tert-butanol by DABCO with simultaneous enzymatic resolution.
  • Keywords
    organocatalysis , Chiral cyclopentenone , pyranone , enzymatic resolution , Rearrangement , isomerisation
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2009
  • Journal title
    Tetrahedron Letters
  • Record number

    1864624