Title of article
Formal total synthesis of borrelidin: synthesis of C1–C11 fragment via desymmetrization strategy
Author/Authors
Yadav، نويسنده , , J.S. and Bezawada، نويسنده , , Padmavani and Chenna، نويسنده , , Venugopal، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
3772
To page
3775
Abstract
A stereoselective formal total synthesis of borrelidin is described. The synthetic strategy for synthesis of C1–C11 fragment features desymmetrization of Diels–Alder adduct, Sharpless asymmetric epoxidation, regioselective opening of chiral epoxide, and alkylation using Evans chiral auxiliary.
Keywords
Borrelidin , desymmetrization , Sharpless asymmetric epoxidation , Evan’s chiral auxiliary
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1864667
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