Title of article
Air-tolerant C–C bond formation via organometallic ruthenium catalysis: diverse catalytic pathways involving (C5Me5)Ru or (C5H5)Ru are robust to molecular oxygen
Author/Authors
Severa، نويسنده , , Luk?? and V?vra، نويسنده , , Jan and Kohoutov?، نويسنده , , Anna and ???kov?، نويسنده , , Martina and ??lov?، نويسنده , , Tereza and H?vl، نويسنده , , Jakub and ?aman، نويسنده , , David and Pohl، نويسنده , , Radek and Adriaenssens، نويسنده , , Louis and Tepl?، نويسنده , , Filip، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
4526
To page
4528
Abstract
Ruthenium-catalyzed substitutions of carbon pronucleophiles, various [2+2+2] cycloadditions, and addition of a diazo compound to an alkyne are shown to proceed in the presence of air. Notably diverse catalytic manifolds remain supported under conditions generally regarded as prohibitive. Building on rare reports from the literature we show that a range of organometallic transformations based on reaction intermediates derived from (C5Me5)Ru or (C5H5)Ru moieties are air-compatible.
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1865239
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