Title of article
Oxidation of benzyl alcohols with difluoro(aryl)-λ3-bromane: formation of benzyl fluoromethyl ethers via oxidative rearrangement
Author/Authors
Ochiai، نويسنده , , Masahito and Yoshimura، نويسنده , , Akira and Miyamoto، نويسنده , , Kazunori، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
4792
To page
4795
Abstract
Oxidative rearrangement of benzyl alcohols with difluoro(p-trifluoromethylphenyl)-λ3-bromane (5 × 10−2 M) in chloroform at room temperature afforded aryl fluoromethyl ethers selectively in good yields, probably via 1,2-shift of aryl groups from benzylic carbon to oxygen atoms.
Keywords
Oxidation , Rearrangement , alcohol , Hypervalent , Bromine , Ether
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1865424
Link To Document