Title of article
Diastereodifferentiating photodimerization of alkyl 2-naphthoates with chiral auxiliaries
Author/Authors
Xu، نويسنده , , Hongxia and Chen، نويسنده , , Bin and Zhang، نويسنده , , Liping and Wu، نويسنده , , Li-Zhu and Tung، نويسنده , , Chen-Ho، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
4965
To page
4968
Abstract
Photodimerization of alkyl 2-naphthoates with chiral auxiliaries resulted in cubane-like anti head-to-head photodimers in 93% yield and with up to 59% diastereomeric excess. After removal of the chiral auxiliaries enantiomers of cubane-like photodimer of 2-naphthalene carboxylic acid were obtained in 80% yield.
Keywords
Chiral auxiliary strategy , diastereoselectivity , Cubane-like photodimer , Photodimerization
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1865547
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