Title of article
Radical-mediated thiodesulfonylation of the vinyl sulfones: access to (α-fluoro)vinyl sulfides
Author/Authors
Sacasa، نويسنده , , Pablo R. and Zayas، نويسنده , , Jessica and Wnuk، نويسنده , , Stanislaw F.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
5424
To page
5427
Abstract
Radical-mediated thiodesulfonylation of the vinyl and (α-fluoro)vinyl sulfones, derived from aldehydes and ketones, with aryl thiols in organic or aqueous medium provided access to vinyl and (α-fluoro)vinyl sulfides. The vinyl sulfides were formed predominantly with E stereochemistry independent of the stereochemistry of the starting vinyl sulfones.
Keywords
Vinyl sulfides , ?-Fluoro vinyl sulfides , Vinyl sulfones , Fluoroalkenes , radical reactions
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1865882
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