Title of article
Synthesis of substituted nortrop-2-enes and 3-vinylpyridin-2-ones via reaction of 1,2,3,4,5,6,7-heptamethoxycarbonylcycloheptatriene with primary amines
Author/Authors
Tomilov، نويسنده , , Yury V. and Platonov، نويسنده , , Dmitry N. and Okonnishnikova، نويسنده , , Galina P.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
5605
To page
5608
Abstract
The mode of reaction of the 1,2,3,4,5,6,7-heptamethoxycarbonylcycloheptatriene with primary amines depends on the reaction conditions and leads to selective formation of N-substituted (heptamethoxycarbonyl)nortrop-2-enes and/or 3-vinylpyridin-2-ones bearing six ester groups. The influence of the solvent on the selectivity of the formation of nortropenes and pyridinones was studied.
Keywords
Cycloheptatrieneheptacarboxylate , Michael addition , Intramolecular cyclization , Pyridinones , Tropene derivatives
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1866004
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