Title of article
Spirolactone syntheses through a rhodium-catalyzed intramolecular C–H insertion reaction: model studies towards the synthesis of syringolides
Author/Authors
Mauricio Navarro Villalobos، نويسنده , , Mauricio and Wood، نويسنده , , John L.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
6450
To page
6453
Abstract
Model studies towards the total synthesis of syringolides using a rhodium-catalyzed intramolecular C–H insertion reaction as the key step are described. A highly stereospecific synthesis of spirolactones is achieved employing this methodology.
Keywords
Syringolides , Rhodium(II) stabilized carbene , C–H insertion , Spirolactones , Stereospecific
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1866599
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