Title of article
Palladium-catalyzed carboxylative cyclization of α-allenyl amines in dense carbon dioxide
Author/Authors
Kayaki، نويسنده , , Yoshihito and Mori، نويسنده , , Naoko and Ikariya، نويسنده , , Takao، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
6491
To page
6493
Abstract
Carboxylative transformation of 2,3-allenic amines into 5-vinyl-1,3-oxazolidin-2-ones was promoted by palladium catalysts under a pressurized CO2 condition. The presence of a stereogenic center adjacent to the allene group resulted in the formation of the corresponding cyclic urethane as a single trans-diastereomer.
Keywords
carbon dioxide fixation , Homogeneous catalysis , PALLADIUM , Allenes , Urethane
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1866633
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