Title of article
Addition of aryl cuprates to azides: a novel approach for the synthesis of unsymmetrical diaryl amines
Author/Authors
Yadav، نويسنده , , J.S. and Reddy، نويسنده , , B.V. Subba and Borkar، نويسنده , , Prashant and Reddy، نويسنده , , P. Janardhan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
6642
To page
6645
Abstract
Aryl and benzyl azides react smoothly with aryl cuprates, generated in situ from aryl magnesium bromide and CuCN in THF to furnish a variety of unsymmetrical diaryl amines in good yields. This is the first report on the synthesis of diarylamines from aryl azides and aryl bromides via an organometallic approach.
Keywords
Grignard reaction , Aryl azides , Aryl cuprates , Diaryl amines
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1866743
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