Title of article
Palladium-catalyzed synthesis of carbazoles from N-(2-halophenyl)-2,6-diisopropylanilines via C–C cleavage
Author/Authors
Chianese، نويسنده , , Anthony R. and Rogers، نويسنده , , Scott L. and Al-Gattas، نويسنده , , Hanna، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
2241
To page
2243
Abstract
The synthesis of 1-isopropyl-substituted carbazoles by the palladium-catalyzed dealkylative cyclization of N-(2-halophenyl)-2,6-diisopropylanilines is described. The reaction involves intramolecular C–C bond formation, coupled with the cleavage of a C–X bond and a C–C bond, and is proposed to proceed through the formation of a dearomatized intermediate.
Keywords
carbazoles , PALLADIUM , Catalysis , cyclization
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1872021
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