Title of article
Synthesis of azidochloromethane and azidobromomethane
Author/Authors
Banert، نويسنده , , Klaus and Joo، نويسنده , , Young-Hyuk and Rüffer، نويسنده , , Tobias and Walfort، نويسنده , , Bernhard and Lang، نويسنده , , Heinrich، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
3
From page
2880
To page
2882
Abstract
By treatment of tris(azidomethyl)amine with dry hydrogen halide, azidochloromethane and azidobromomethane were prepared. The former product, which is more stable than the latter, was isolated as a colorless liquid. The desired azidohalomethanes are intermediates in the nucleophilic substitution of dihalomethanes to generate diazidomethane but could not be detected in this transformation.
Keywords
Azides , Hazardous compounds , nucleophilic substitution , Triazoles
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1872221
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