Title of article
An unexpected coupling reaction between isocyanides and carboxylic acids: a method for the synthesis of highly stable symmetrical and unsymmetrical alkylamidine and arylamidine carbocations
Author/Authors
Shaabani، نويسنده , , Ahmad and Rezayan، نويسنده , , Ali Hossein and Sarvary، نويسنده , , Afshin and Keshipour، نويسنده , , Sajjad and Khavasi، نويسنده , , Hamid Reza، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
4
From page
4091
To page
4094
Abstract
An unexpected coupling reaction between isocyanides and carboxylic acids which led to the synthesis of highly stable symmetrical and unsymmetrical alkylamidine and arylamidine carbocations under mild reaction conditions is described. The structures of these compounds were confirmed by IR, mass, 1H NMR, 13C NMR, and single-crystal X-ray diffraction studies and a plausible mechanism is proposed.
Keywords
isocyanide , Carboxylic acid , Stable carbocation
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1873846
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