Title of article
Computational comparison of Rh2(esp)2 and Rh2(O2CH)4 as catalysts in a carbenoid reaction
Author/Authors
Dennis Bonge، نويسنده , , Hanne Therese and Hansen، نويسنده , , Tore، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
4
From page
5298
To page
5301
Abstract
A computational study of Rh2(esp)2-catalysed cyclopropanation of styrene with ethyl bromodiazoacetate is presented. The calculated structures and the energy profile of the reaction show a high level of similarity between Rh2(esp)2, a catalyst with sizeable, tethered ligands, and the simplified model catalyst Rh2(O2CH)4.
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1874876
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