Title of article
Spiroborate catalyzed reductions with N,N-diethylaniline borane
Author/Authors
Coleridge، نويسنده , , Brian M. and Angert، نويسنده , , Thomas P. and Marks، نويسنده , , Lucas R. and Hamilton، نويسنده , , Patrick N. and Sutton، نويسنده , , Christopher P. and Matos، نويسنده , , Karl and Burkhardt، نويسنده , , Elizabeth R.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
4
From page
5973
To page
5976
Abstract
Reduction of esters, amides, and ketones by N,N-diethylaniline borane is accelerated by catalysts derived from spiroborate complexes. Esters are reduced at ambient temperature in less than 4 h with this amine borane and 5 mol % spiroborate 6. Functional group selectivity shows ketone and tertiary amide reduction is faster than ester or nitrile reduction.
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1875431
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