Title of article
An economic and efficient tetrahydrofuranylation of alcohols, imines and alkynes
Author/Authors
Troisi، نويسنده , , Luigino and Granito، نويسنده , , Catia and Ronzini، نويسنده , , Ludovico and Rosato، نويسنده , , Francesca and Videtta، نويسنده , , Valeria، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
4
From page
5980
To page
5983
Abstract
The tetrahydrofuranyl radical, generated by heating tetrahydrofuran in the presence of air and allyl or benzyl chloride, becomes a useful tool in order to transform the hydroxyl functions into ethers, or the CN double bond into amine, or the C–C triple bond into vinyl derivatives. A radical mechanism is proposed followed by a nucleophilic substitution for the alcohol substrate and a radical addition for the iminic and the acetylenic reactants.
Keywords
alcohols , Alkynes , imines , radical reactions , Tetrahydrofuranylation
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1875437
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