Title of article
Gold-catalyzed rearrangement of substituted allyl aryl ethers
Author/Authors
Vyvyan، نويسنده , , James R. and Dimmitt، نويسنده , , Heidi E. and Griffith، نويسنده , , Jennifer K. and Steffens، نويسنده , , Laura D. and Swanson، نويسنده , , Rebecca A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
4
From page
6666
To page
6669
Abstract
Triphenylphosphinegold(I) complexes catalyze the Claisen-type rearrangement of aryl allyl ethers to the corresponding branched and linear products. The product distribution depends on the olefin geometry of the allylic ether. Stereochemical transfer experiments support an ionic mechanism.
Keywords
Claisen rearrangement , Mitsunobu etherification , gold catalysis , Lewis acid
Journal title
Tetrahedron Letters
Serial Year
2010
Journal title
Tetrahedron Letters
Record number
1875988
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