Title of article
A highly stereoselective approach to tetrasubstituted (E)-β-hydroxy silyl enol ethers by addition of aryl-substituted oxiranyl anions to acylsilanes
Author/Authors
Wang، نويسنده , , Cheng and Gan، نويسنده , , Zubao and Lu، نويسنده , , Ji and Wu، نويسنده , , Xia and Song، نويسنده , , Zhenlei، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
2462
To page
2464
Abstract
A highly stereoselective approach to tetrasubstituted (E)-β-hydroxy silyl enol ethers is described. The reaction proceeds via a sequential addition/[1,2]-Brook rearrangement/epoxide-opening process of aryl-substituted oxiranyl anions with acylsilanes.
Keywords
Acylsilane , Oxiranyl anion , Brook rearrangement , Silyl enol ether
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878065
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