Title of article
Preparation of phenalenes and hydronaphthacenes through tandem alkyne Fischer–carbene complex coupling and inter- or intra-molecular Diels–Alder reactions
Author/Authors
Patti، نويسنده , , Rajesh Kumar and Duan، نويسنده , , Shaofeng and Wang، نويسنده , , Zhipeng and Herndon، نويسنده , , James W.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
4182
To page
4185
Abstract
The rapid construction of phenalenes through the reaction of 8-alkynyltetralones with Fischer–carbene complexes followed by either an inter- or intra-molecular Diels–Alder reaction is presented. As a showcase of the synthetic utility of this process, the rapid construction of polycyclic ring systems containing the tetracycline core has been demonstrated through an iterative application of this reaction sequence.
Keywords
Carbene complexes , isobenzofurans , cycloaddition , Phenalenes , Alkynes , Naphthacenes
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1878967
Link To Document