Title of article
A chromium-free synthesis of enantiopure 5-oxoborneol
Author/Authors
Pierluigi and Tartaggia، نويسنده , , Stefano and Padovan، نويسنده , , Pierluigi and Borsato، نويسنده , , Giuseppe and De Lucchi، نويسنده , , Ottorino and Fabris، نويسنده , , Fabrizio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
4478
To page
4480
Abstract
Enantiopure (−)-5-oxoborneol was obtained in 35% overall yield in two steps, starting from readily available (−)-bornyl acetate and using oxone® as a safe and inexpensive oxidant. The reported procedure avoids the use of large excess of noxious chromium(VI), which was required by the so far reported syntheses.
Keywords
Oxone® , Ruthenium , terpene , Borneol , Camphor , Catalysis , Oxidation
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1879098
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