Title of article
Radical-mediated intramolecular C–C bond formation and the deoxygenation of alcohols under solvent-free conditions with tributyl methyl ammonium hypophosphite
Author/Authors
Lee، نويسنده , , Eun Hwa and Cho، نويسنده , , Dae Hyan and Satyender، نويسنده , , Apuri and Jang، نويسنده , , Doo Ok، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
6927
To page
6929
Abstract
A green, solvent-free protocol was developed for the radical-mediated intramolecular cyclization of haloacetals and the deoxygenation of S-methyl dithiocarbonates and cyclic thionocarbonate. This process uses tributyl methyl ammonium hypophosphite as a H-donor in the presence of triethylborane or t-butyl peroxide. This methodology provides eco-friendly reaction conditions.
Keywords
C–C bond formation , deoxygenation , Radical reaction , solvent-free
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1879745
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