• Title of article

    Catalytic C–H arylation of unactivated heteroaromatics with aryl halides by cobalt porphyrin

  • Author/Authors

    Qian، نويسنده , , Ying Ying and Wong، نويسنده , , Ka Lai and Zhang، نويسنده , , Meng Wen and Kwok، نويسنده , , TSZ Yiu and Lam، نويسنده , , Ching Tat and Chan، نويسنده , , Kin Shing، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2012
  • Pages
    5
  • From page
    1571
  • To page
    1575
  • Abstract
    Direct C–H arylation of unactivated heteroaromatics with aryl halides catalyzed by cobalt porphyrin is reported. The reaction is proposed to go through a homolytic aromatic substitution reaction. The aryl radical is electrophilic and a SOMO–HOMO interaction is predominant in the aryl radical addition process.
  • Keywords
    C–H arylation , heteroaromatics , Heterobiaryl , Cobalt porphyrin
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2012
  • Journal title
    Tetrahedron Letters
  • Record number

    1880319