Title of article
Formal synthesis of (−)-stemoamide using a useful epimerization at C-8
Author/Authors
Chavan، نويسنده , , Subhash P. and Harale، نويسنده , , Kishor R. and Puranik، نويسنده , , Vedavati G. and Gawade، نويسنده , , Rupesh L.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
2647
To page
2650
Abstract
The formal synthesis of (−)-stemoamide was achieved starting from l-pyroglutamic acid. The key steps used are the allylation using BF3·OEt2, ring closing metathesis, allylic oxidation and a novel epimerization at C8.
Keywords
allylation , allylic oxidation , pyroglutamic acid , Stemoamide , Ring closing metathesis
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1880783
Link To Document