Title of article
Reactions of 1,1-diaryl-2-isopropylidene-3-methylenecyclopropanes with C,N-diarylnitrones and nitrile oxides
Author/Authors
Stepakov، نويسنده , , Alexander V. and Larina، نويسنده , , Anna G. and Boitsov، نويسنده , , Vitaly M. and Molchanov، نويسنده , , Alexander P. and Gurzhiy، نويسنده , , Vladislav V. and Starova، نويسنده , , Galina L.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
5
From page
3411
To page
3415
Abstract
The reactions of unactivated bis(methylene)cyclopropanes with nitrones and nitrile oxides have been investigated. The 1,1-diaryl-2-isopropylidene-3-methylenecyclopropanes react with the C,N-diarylnitrones to give a mixture of 2,2-dimethyl-1,6-diaryl-3-(diarylmethylene)piperidin-4-ones and 5-methyl-1-aryl-1-(arylamino)-4-(diarylmethylene)hex-5-en-3-ones. 2,3-Dihydro-3-methylenepyridin-4(1H)-ones are obtained by reaction of 1,1-diaryl-2-isopropylidene-3-methylenecyclopropanes with nitrile oxides.
Keywords
3-dipolar cycloaddition , 2-Isopropylidene-3-methylenecyclopropanes , Nitrile oxides , Nitrones , 3-Methylenepiperidin-4-ones , 2 , 3-Dihydro-3-methylenepyridin-4(1H)-ones , 1
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1881084
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