Title of article
Oxidative transformation of azides to aryl nitriles using DIB/TBHP: scope and mechanistic insights
Author/Authors
Zhao، نويسنده , , Ying-Yi and Chew، نويسنده , , Xinying and Leung، نويسنده , , Gulice Y.C and Yeung، نويسنده , , Ying-Yeung and Corey، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
4766
To page
4769
Abstract
Bis(tert-butylperoxy)iodobenzene, generated in situ by the reaction between diacetoxyl iodobenzene (DIB) and tert-butyl hydroperoxide (TBHP), was used in the oxidative transformation of primary azides to nitriles, and secondary azides to ketones.
Keywords
Oxidation , hypervalent iodine , Nitrile , Selectivity , Mechanism
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1881694
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