Title of article
Asymmetric induction by helical poly(amino acid)s in cyanosilylation of aldehydes
Author/Authors
Akagawa، نويسنده , , Kengo and Kudo، نويسنده , , Kazuaki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
3
From page
5981
To page
5983
Abstract
It was first demonstrated that helical poly(amino acid)s have an ability to induce enantioselectivity in the cyanosilylation of aldehydes. The helicity of poly(amino acid)s and the N-terminal amino group were essential for the enantioinduction of the reaction.
Keywords
Asymmetric induction , Cyanosilylation , Poly(amino acid)s , Polyleucine , ?-helix
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1882541
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