Title of article
Unique trifurcated hydrogen bonding in a pseudopolymorph of tricyclohexane triperoxide (TCTP) and its thermal studies
Author/Authors
Neupane، نويسنده , , Chiranjeev Sharma and Awasthi، نويسنده , , Satish Kumar، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
6067
To page
6070
Abstract
Tricyclohexane triperoxide (TCTP) was synthesized as a main by-product of tetraoxane synthesis and was characterized by spectroscopic techniques viz. 1H NMR, 13C NMR, FT-IR and Raman. The single crystal X-ray structure revealed the inclusion of solvent in 1:1 stoichiometric ratio involving a unique trifurcated C(sp3)–H⋯O hydrogen bonding imparting remarkable symmetry to the molecule. The thermal stability of single crystal was determined by TG-DTA and DSC.
Keywords
Hydrogen bonding , Tricyclohexane triperoxide , Pseudopolymorphism , thermal stability , single crystal XRD
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1882595
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