Title of article
Palladium-catalyzed allylation of 2,2,2-trifluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile
Author/Authors
Zhang، نويسنده , , Wei and Zhao، نويسنده , , Yanchuan and Ni، نويسنده , , Chuanfa and Mathew، نويسنده , , Thomas and Hu، نويسنده , , Jinbo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
6565
To page
6568
Abstract
A palladium-catalyzed allylation reaction of PhSO2CH2CF3 (2) with a variety of allyl carbonates has been successfully developed for selective 2,2,2-trifluoroethylation under neutral conditions. With this method, the 1-phenylsulfonyl-2,2,2-trifluoroethyl moiety was efficiently transferred into organic compounds without the competing β-elimination of fluoride, to afford a range of mono-allylated and di-allylated compounds.
Keywords
fluorine , Trifluoroethylation , Palladium catalysis , allylation , Trifluoroethyl sulfone
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1882824
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