Title of article
In situ generation of hydroperoxide by oxidation of benzhydrols to benzophenones using sodium hydride under oxygen atmosphere: use for the oxidative cleavage of cyclic 1,2-diketones to dicarboxylic acids
Author/Authors
Kang، نويسنده , , Sunhae and Lee، نويسنده , , Soyoung and Jeon، نويسنده , , Minju and Kim، نويسنده , , Sun Min and Kim، نويسنده , , Young Sug and Han، نويسنده , , Hogyu and Yang، نويسنده , , Jung Woon، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
373
To page
376
Abstract
A facile oxidative cleavage of cyclic 1,2-diketones 1 to dicarboxylic acids 3 with hydroperoxide generated in situ has been developed. In situ generation of hydroperoxide was effected by the oxidation of 4,4′-dichlorobenzhydrol 2f to 4,4′-dichlorobenzophenone 4f using sodium hydride under oxygen atmosphere.
Keywords
Sodium hydride , Benzhydrol , Cyclic 1 , 2-Diketone , Oxidative cleavage , Dicarboxylic acid
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1883497
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