Title of article
Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system
Author/Authors
Charlton، نويسنده , , Adam and Donati، نويسنده , , Donato and Fusi، نويسنده , , Stefania and Murphy، نويسنده , , Patrick J. and Ponticelli، نويسنده , , Fabio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
1227
To page
1229
Abstract
Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.
Keywords
Tetrathienyltetrathiafulvalene , 2-Dioxethanes , 1 , Cyclic disulfides , 1 , 2-Dithioethenes , singlet oxygen
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1883872
Link To Document