Title of article
Simple and clean synthesis of ketones from internal olefins using PdCl2/N,N-dimethylacetamide catalyst system
Author/Authors
Mitsudome، نويسنده , , Takato and Yoshida، نويسنده , , Syuhei and Tsubomoto، نويسنده , , Yamato and Mizugaki، نويسنده , , Tomoo and Jitsukawa، نويسنده , , Koichiro and Kaneda، نويسنده , , Kiyotomi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
1596
To page
1598
Abstract
A simple catalytic system consisting of PdCl2 and N,N-dimethylacetamide enabled clean and selective synthesis of ketones from internal olefins using molecular oxygen. Various functionalized internal olefins were directly and regioselectively oxidized; C atoms of CC bonds far from substituted moieties were preferably oxidized.
Keywords
PALLADIUM , Regioselective oxidation , Internal olefin , N-dimethylacetamide , N
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884029
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