Title of article
Unexpected formation of a 1,2-diketone from a 1,3-diketone mediated by lanthanides
Author/Authors
Ilya V. Taydakov، نويسنده , , Ilya V. and Nelyubina، نويسنده , , Yulia V.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
1704
To page
1706
Abstract
The first example of the formation of a 1,2-heteroaromatic diketone from a 1,3-diketone by air oxidation mediated by lanthanides is described. The structures of the products are confirmed by X-ray single crystal diffraction and NMR spectroscopy. A possible reaction mechanism is proposed.
Keywords
1 , Lanthanides , Pyrazole , 1 , 3-diketones , 2-diketones
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884088
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