Title of article
A new method using 2-chloro-4,6-dimethoxy-1,3,5-triazine for facile elimination of dimethylamino group in Eschenmoser’s methylenation for synthesis of α,β-unsaturated esters
Author/Authors
Yamada، نويسنده , , Kohei and Masaki، نويسنده , , Kazumasa and Hagimoto، نويسنده , , Yuri and Kamiya، نويسنده , , Seina and Kunishima، نويسنده , , Munetaka، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
1758
To page
1760
Abstract
A facile one-step method for the elimination of the dimethylamino group in Eschenmoser’s methylenation has been developed using a combination of 2-chloro-4,6-dimethoxy-1,3,5-triazine and triethylamine. The chemoselective elimination of the dimethylamino group occurred in compounds possessing either a diethylamino group or an alkylsulfanyl group.
Keywords
6-dimethoxy-1 , 2-Chloro-4 , Eschenmoser’s methylenation , 3 , 5-triazine (CDMT) , ? , ?-unsaturated esters
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884118
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