Title of article
Studies on the ring-opening of bicyclic cyclopropanes activated by a carbonyl group
Author/Authors
Jiang، نويسنده , , Xiaojian and Lim، نويسنده , , Zonghan and Yeung، نويسنده , , Ying-Yeung and Corey، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
1798
To page
1801
Abstract
Studies on the Friedel–Crafts reaction between carbonyl bicyclic cyclopropane and electronic-rich aromatic systems were conducted. Lewis acid and iminium cationic activation methods were examined. It was found that the cyclopropane ring-opening was highly dependent on the nature of the counter nucleophile as well as the activation method.
Keywords
Cyclopropane , Friedel–Crafts , Lewis acid , Selectivity , Mechanism
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884127
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