Title of article
Reversible sequestering of CO2 on a multiporous crystalline framework of 2-quinolyl-porphyrin
Author/Authors
Silva، نويسنده , , Joana de A. e and Domingos، نويسنده , , Valdemar F. and Marto، نويسنده , , Daniela da Costa and Serra، نويسنده , , Leticia D. and Marcos، نويسنده , , Mariana and Silva، نويسنده , , Manuela R. and Gil، نويسنده , , Joمo M. and Sobral، نويسنده , , Abilio J.F.N. and Melo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
2449
To page
2451
Abstract
In this Letter we describe the synthesis and characterization of a new multiporous crystalline framework based on meso-tetra-(2-quinolyl)-porphyrin, that presents crystal channels adequate for CO2 reversible sequestering, from 1 to 5 bar of CO2 pressures. This behaviour is very different from the parent meso-tetraphenyl-porphyrin, which points to an important favourable interaction of CO2 with meso-substituted nitrogen aromatic porphyrin free bases.
Keywords
Carbon dioxide , Porphyrin , Quinoline
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884383
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