Title of article
A novel one-pot synthesis of cyclopropanols based on the reaction of magnesium carbenoids with lithium enolate of ketones
Author/Authors
Kashiwamura، نويسنده , , Gaku and Kimura، نويسنده , , Tsutomu and Satoh، نويسنده , , Tsuyoshi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
2533
To page
2535
Abstract
The reaction of magnesium carbenoids with lithium enolate of ketones resulted in the formation of cyclopropanols in moderate to good yields. These reactive species (i.e., magnesium carbenoids and lithium enolate of ketones) were generated from 1-chloroalkyl p-tolyl sulfoxides with i-PrMgCl and ketones with LDA in the reaction medium at −78 °C in a one-pot reaction.
Keywords
Cyclopropane , Cyclopropanol , lithium enolate , Magnesium carbenoid , one-pot synthesis
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884419
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