Title of article
Copper-catalyzed enantioselective allylic oxidation of acyclic olefins
Author/Authors
Zhang، نويسنده , , Bo and Zhu، نويسنده , , Shou-Fei and Zhou، نويسنده , , Qi-Lin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
2665
To page
2668
Abstract
A copper-catalyzed asymmetric allylic oxidation of acyclic olefins has been developed. By using the complexes of copper and chiral spiro bisoxazoline ligands as catalysts, the oxidation of various acyclic olefins was accomplished with excellent regioselectivity (>20:1 in most cases) and up to 67% ee under mild reaction conditions, which represents one of the best results for the enantioselective allylic oxidation of acyclic olefins.
Keywords
asymmetric allylic oxidation , Copper catalysis , Acyclic olefin , Chiral spiro ligands
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884477
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