Title of article
Copper-Catalyzed Aerobic Oxidative Amination of Arylboronic Acid with Aminal under Base-Free Conditions
Author/Authors
Zhou، نويسنده , , Yanping and Xie، نويسنده , , Yinjun and Yang، نويسنده , , Lei and Xie، نويسنده , , Pan Ming Huang، نويسنده , , Hanmin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
2713
To page
2716
Abstract
A new process involving copper-catalyzed oxidative amination reaction of various arylboronic acids with aminals under mild conditions has been developed. The key copper-amide species involved in the C–N bond-forming process was generated via C–N bond cleavage of aminal under base-free conditions. Moderate yields of desired amination products can be obtained under mild conditions when air was served as oxidant and PhCO2H was used as an additive.
Keywords
Oxidative amination , C–N cleavage , Base-free , Aminal , Copper
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884499
Link To Document