Title of article
Ring rearrangement metathesis of 2-allylbicyclo[2.2.2]octenes: a short entry to cis-hydrindenols from 2-methoxyphenols
Author/Authors
Tsao، نويسنده , , Kuo-Wei and Devendar، نويسنده , , Badugu and Liao، نويسنده , , Chun-Chen، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
5
From page
3055
To page
3059
Abstract
We described the highly efficient synthesis of cis-hydrindenols from 2-allylbicyclo[2.2.2]octenol derivatives using the Diels–Alder adducts of masked o-benzoquinones (MOBs) with suitable dienophiles, as precursors for ring-rearrangement metathesis (RRM). These facile, versatile, and operationally simple transformation strategies produced cis-hydrindenol products with four stereo-centers and a tertiary hydroxyl functional group.
Keywords
Masked o-benzoquinones , Diels–Alder reactions , Ring-rearrangement metathesis , cis-Hydrindenol
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884638
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