Title of article
Unexpected opening of steroidal E-ring during hypoiodite-mediated oxidation
Author/Authors
Kou، نويسنده , , Yi and Lee، نويسنده , , Seongmin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
4106
To page
4109
Abstract
In this Letter, we report unexpected formation of E-ring opened steroidal alkaloid from primary amine presumably via a hypoiodite-mediated iodoamination followed by fragmentation of sterically congested iodospiroaminal.
Keywords
Hypoiodite , Aminyl radical cyclization , Steroidal alkaloid , Solasodine , Steroidal ring opening
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1885085
Link To Document