Title of article
Carbenic philicity and the ‘intrinsic reactivity index’
Author/Authors
Moss، نويسنده , , Robert A. and Krogh-Jespersen، نويسنده , , Karsten، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
4303
To page
4305
Abstract
The reactivity of electrophilic, ambiphilic, and nucleophilic singlet carbenes is considered in terms of a recently proposed ‘intrinsic reactivity index’ (IRI). Comparisons of IRI are made with previously described analyses, and it is concluded that IRI is not as useful for the determination or analysis of carbene philicity as FMO-based or empirical treatments.
Keywords
Singlet carbenes , Frontier molecular orbital energies , Reactivity indices
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1885163
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