Title of article
The triazolyl analogue of the trityl cation
Author/Authors
Oukessou، نويسنده , , Mohamed and Génisson، نويسنده , , Yves and El Arfaoui، نويسنده , , Dounia and Ben-Tama، نويسنده , , Abdeslem and El Hadrami، نويسنده , , El Mestafa and Chauvin، نويسنده , , Remi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
4362
To page
4364
Abstract
The formation of the tris(3-benzyl-triazol-5-yl)carbenium cation, a heterocyclic analogue of the trityl cation, from tris(3-benzyl-triazol-5-yl)methanol, itself generated by Cu(I)-catalyzed Huisgen reaction of benzyl azide with triethynylmethanol, in the presence of trifluoroacetic anhydride is evidenced through a selective SN1 reactivity with various O-, N-, S-, and C-nucleophiles, giving the corresponding triazolylmethane derivatives in moderate to high yields.
Keywords
Carbenium , Trityl cation , tris(1 , 2 , 3-triazolyl)methanol , Tris(triazolyl)methylium
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1885189
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