Title of article
Iron-catalyzed alkenylation of cyclic ethers via decarboxylative sp3(C)–sp2(C) coupling
Author/Authors
Zhao، نويسنده , , Jincan and Zhou، نويسنده , , Wei and Han، نويسنده , , Jianlin and Li، نويسنده , , Guigen and Pan، نويسنده , , Yi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
6507
To page
6510
Abstract
An efficient Fe(acac)3-catalyzed decarboxylative C(sp2)–C(sp3) coupling reaction via oxidation of C–H bond adjacent to an oxygen atom has been developed successfully, in which cyclic ethers are selectively transformed into the corresponding alkenylation products with good chemical yields and excellent stereoselectivities. The mechanism was studied and the reaction was supposed to proceed through a radical oxidative coupling process.
Keywords
Alkenylation , Coupling , Decarboxylative , Oxidation , Fe(acac)3
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1886753
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