Title of article
Borylation using group IV metallocene under mild conditions
Author/Authors
Marciasini، نويسنده , , Ludovic D. and Vaultier، نويسنده , , Jean-Michel and Pucheault، نويسنده , , Mathieu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
1702
To page
1705
Abstract
A borylation reaction of aromatic diazonium salts has been optimized using titanocene and zirconocene derivatives as catalysts. The reaction employs diisopropylaminoborane as a borylating agent and proceeds smoothly at room temperature to provide arylboronates after methanolysis and transesterification with pinacol. The reaction mechanism has been found to proceed via a radical pathway.
Keywords
boron , Metallocene , zirconium , radical , Titanium
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1888446
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