Title of article
Change of mechanism with a change of substituents for a Zincke reaction
Author/Authors
Rezende، نويسنده , , Marcos Caroli and Ponce، نويسنده , , Ingrid and Oٌate، نويسنده , , Rubén and Almodovar، نويسنده , , Iriux and Aliaga، نويسنده , , Carolina، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
3
From page
3097
To page
3099
Abstract
The reaction between N-(2,4-dinitrophenyl)-4-(4-pyridyl)pyridinium chloride and 4-aminothiophenol led to an unexpected displacement of the 2,4-dinitrophenyl group, in contrast with the normal Zincke product formed with other nucleophilic 4-substituted anilines. Evidence for a SET process was obtained from EPR spectra of the reaction mixture.
Keywords
SET process , Unexpected displacement product , Zincke reaction , 4-Substituted anilines
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1889474
Link To Document