Title of article
A simple method for desymmetrizing 1,1′-ferrocenedicarboxaldehyde
Author/Authors
Benniston، نويسنده , , Andrew C. and Sirbu، نويسنده , , Dumitru and Turta، نويسنده , , Constantin and Probert، نويسنده , , Michael R. and Clegg، نويسنده , , William، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
3777
To page
3780
Abstract
A simple chromatography-free method for desymmetrizing ferrocene is described starting from the readily available dialdehyde. Oxidation of 1,1′-ferrocenedicarboxaldehyde in a water/acetonitrile mixture with KMnO4 produced 1′-formyl-ferrocenecarboxylic acid. The same reaction carried out in a water/acetone mixture produced 1′-[(E)-3-oxo-but-1-enyl]-ferrocenecarboxylic acid.
Keywords
Oxidation , Carboxylic acid , desymmetrization , Michael addition , Ferrocene
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1889928
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