• Title of article

    Targeted synthesis of 2,3-disubstituted 2-phospholenes using catalytic cycloalumination of acetylenes

  • Author/Authors

    D’yakonov، نويسنده , , Vladimir A. and Makhamatkhanova، نويسنده , , Alevtina L. and Agliullina، نويسنده , , Rina A. and Tyumkina، نويسنده , , Tat’yana V. and Dzhemilev، نويسنده , , Usein M.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2014
  • Pages
    3
  • From page
    3913
  • To page
    3915
  • Abstract
    A preparative one-pot method for the synthesis of 2,3-dialkyl-substituted phosphol-2-enes by catalytic cycloalumination of symmetric acetylenes with AlEt3 catalyzed by Cp2ZrCl2 is developed. The reaction gives the corresponding aluminacyclopentenes, which then react in situ with phosphorus dihalides.
  • Keywords
    Aluminacyclopentenes , Phospholenes , Metal complex catalysis , Aluminum compounds , Zirconium complexes , Dzhemilev reaction
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2014
  • Journal title
    Tetrahedron Letters
  • Record number

    1890012