Title of article
Targeted synthesis of 2,3-disubstituted 2-phospholenes using catalytic cycloalumination of acetylenes
Author/Authors
D’yakonov، نويسنده , , Vladimir A. and Makhamatkhanova، نويسنده , , Alevtina L. and Agliullina، نويسنده , , Rina A. and Tyumkina، نويسنده , , Tat’yana V. and Dzhemilev، نويسنده , , Usein M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
3
From page
3913
To page
3915
Abstract
A preparative one-pot method for the synthesis of 2,3-dialkyl-substituted phosphol-2-enes by catalytic cycloalumination of symmetric acetylenes with AlEt3 catalyzed by Cp2ZrCl2 is developed. The reaction gives the corresponding aluminacyclopentenes, which then react in situ with phosphorus dihalides.
Keywords
Aluminacyclopentenes , Phospholenes , Metal complex catalysis , Aluminum compounds , Zirconium complexes , Dzhemilev reaction
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1890012
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