Title of article
Channel-dependent conformations of single-strand polymers in organic networks composed of tetrapodal adamantanes with N-heterocyclic moieties
Author/Authors
Tominaga، نويسنده , , Masahide and Iekushi، نويسنده , , Akitaka and Katagiri، نويسنده , , Kosuke and Ohara، نويسنده , , Kazuaki and Yamaguchi، نويسنده , , Kentaro and Azumaya، نويسنده , , Isao، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
5789
To page
5792
Abstract
Three tetrapodal adamantanes bearing imidazole (1), benzimidazole (2), and phenylimidazole (3) moieties were designed and synthesized. The co-crystallization of polyethylene glycol (PEG) and tetrapodal molecules provided polymer-inclusion organic crystals (1a–3a). Single crystal X-ray analysis revealed that organic networks possessing various channels were produced by CH/N and CH/π interactions. The PEG chain had zigzag, kink-type, and helical conformations.
Keywords
Organic network , Polymer inclusion , co-crystal , Channel , Adamantane
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1890925
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