• Title of article

    Indium trichloride catalyzed sp3 C–H bond functionalization of 2-alkyl azaarenes under microwave irradiation

  • Author/Authors

    Chatterjee، نويسنده , , Sourav and Bhattacharjee، نويسنده , , Pinaki and Temburu، نويسنده , , Jagadeesh and Nandi، نويسنده , , Debkumar and Jaisankar، نويسنده , , Parasuraman، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2014
  • Pages
    4
  • From page
    6680
  • To page
    6683
  • Abstract
    Microwave promoted indium trichloride (10 mol %) catalyzed sp3 C–H bond functionalization of 2-alkyl azaarenes 1 or 4 has been observed to construct C–C bond either with but-2-ene-1,4-diones 2 or (E)-3-(2-oxo-2-phenylethylidene)indolin-2-one (6) giving access to 2-((quinolin-2-yl)methyl)butane-1,4-diones 3, 2-((pyridin-2-yl)methyl)butane-1,4-diones 5, or 3-(quinolin-2-yl)propan-2-yl)indolin-2-ones 7 in good yields using 1,4-dioxane as solvent.
  • Keywords
    indium trichloride , microwave irradiation , Azaarene , Enedione , sp3 C–H bond functionalization
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2014
  • Journal title
    Tetrahedron Letters
  • Record number

    1891341