Title of article
Bromodifluoromethylation of aromatic Grignard reagents with CF2Br2
Author/Authors
Shiosaki، نويسنده , , Masahiro and Inoue، نويسنده , , Munenori، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
5
From page
6839
To page
6843
Abstract
The bromodifluoromethylation of aromatic Grignard reagents having electron-withdrawing groups with dibromodifluoromethane (CF2Br2) was developed. The reaction proceeded to give the corresponding (bromodifluoromethyl)benzene derivatives via a difluorocarbene-mediated mechanism.
Keywords
Organofluorine compounds , Bromodifluoromethylation , Aromatic Grignard reagents , difluorocarbene , Dibromodifluoromethane
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1891401
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